Thalladi, Venkat R.
Hydrogen bonding complementarily between hydroxy and amino groups is explored in the creation of three-component supramolecular solid solutions. Binary cocrystals of hydroquinone with p-toluidine, p-chloroniline, p-bromoaniline, and p-iodoaniline and ternary solid solutions containing hydroquinone and two different anilines are prepared. Synthesis of complementary cocrystals and solid solutions involving p-phenylenediamine and para substituted phenols is performed. Results from various syntheses, molecular and solid state characterization of products, and crystal structures of eight complexes, six cocrystals and two solid solutions, are described.
Worcester Polytechnic Institute
Major Qualifying Project
Access to this report is limited to members of the WPI community. Please contact a project advisor or their department to request access
Restricted-WPI community only
Chemistry and Biochemistry